作者:刘路加 ,R.G.Anthony 时间:1983-01-01 点击数:
刘路加
,R.G.Anthony
1:美国德克萨斯州A&M大学化工系 教授
摘要(Abstract):
本文介绍了作者使用经过氨及稀土金属化合物离子交换的分子筛催化剂在流化床反应器中进行甲醇催化转化的研究结果。在常压,430~480℃,重时空速0.1~0.4时~(-1),催化剂停留时间45~70分钟时,甲醇转化为乙烯、丙烯、丙烷的选择性可达80%。对催化剂停留时间、温度、空速及稀释剂对产品分布的影响、也作了研究。
关键词(KeyWords):
Abstract:
Keywords:
基金项目(Foundation):
作者(Author):刘路加
Email:
参考文献(References):
[1] “Coal Will Underpin Chemical Industry”21,Can.Chem.Proc.,Aug.1979.
[2] Kam,A.Y.,W.Lee,et al,“Fluid Bed Process Studies on Selective Conversion of Methanol to High Octane Gascline”,Final Report,Mobil Reseacrh & Development Corporation,(1978)
[3] Singh,B.B.,“Catalytic Conversion of Methanol to Low Molecular Weight Hydrocarbons”,Ph.D.Dissertation,Dec.1979 Texas A &M University.
[4] Koch,J.“Production of Primary Petrochemical Products from Sythesis Gas”,Erdoel Kohle,Erdgas,Petrochem 1981,34(12) 577-61.
[5] Anthony,R.G.,and B.B.Singh,“Olefins from Coal Via Methanol”,Hydrocarbon Processing,March 1981,85-88.
[6] Lin,F.N.,J.C.Chao,and R.G.Anthony,“Conversion of Coalbased Methanol to Ethylene”,Presented at AIChE Annual meeting,New York,Nov.1977,and subsequently published in Coal Processing Technology,Vol Ⅳ,CEP,73-75(1978) .
[7] Chang,Clarence D.,William H.Lang,and Anthony J.Silvestri,“Manufacture of Light olefins”,U.S.Patent 4 062 905(Dec.13,1977) ,assigned to Mobil.
[8] Givens,Edwin N.,Charles J.Plank,and Edward J,Rosinski,“Manufacture of Light olefins”,U.S.Patent 4 079 095(March 14,1978) ,assigned to Mobil.
[9] Singh.B.B.,F.N.Lin,and R.G.Anthony,“Catalytic Conversion of Methanol to Low Molecular Weight 01efins”,Chem.Eng.Commun.4,749-758(1980) .
[10] Anthony,R.G.and B.B.Singh,“Kinetic Analysis of Complex Reaction Systems-Methanol Conversion to Low Mole cnlar Weight olefins”Chem.Eng.Commun.6,214-215(1980) .
[11] Cobb,J.T.,V.T.Coon and P.Tipnis,“Screening of Zeolite Catalysts for Methanol Conversion to Light Hydrocabons”,Final Report,DOE CONTRACT no.EW-78-S-024691,(Sep.1978) ,University of Pittsburgh,PA.
[12] Tipnis,Prasad R.,“Methanol Conversion to Light Hydyocarbons on Zeolite Catalyst”,M.S.Thesis,1978,University of Pittsburgh,PA.
[13] Chang,C.D.and Anthony J.Silvestri,“The Conversion of Methanol and Other O-compounds to Hydrocarbons over Zeolite Catalysts”,J.of Catalyst 47,249-259(1977) .
[14] Van Hooff,J.H.C.,“The Conversion of Methanol to Hydrocarbons Using a New Type of Zeolite as Catalyst”,Presented at the NATO Conference on Chemical Engineering of Catalysis,Nordwickhout,Netherlands,Aug,1979.
[15] Wolthuizen,J.P.,J.P.Van der Burg and J.H.C.Van Hooff,“Low Temperature Reaction of Olefins on partially Hydrated Zeolite H-ZSM-5”,Catalysis by Zeolites,(Ed.by B.Imelik et al)P85 Elsevier Scientific Publishing Co.,Amsterdam(1980) .
[16] Anthony,R.G.,B.B.Singh and E.Vera C.,“Selectivity Data and Emperical Equations for Methanol Conversion to Low Molecular Weight Hydrocarbons”,Presented at the Houston Petrochem.Show and National AIChE Meeting(March,1981) .
[17] Chaug,C D.,“A Kinetic Model for Methanol Conversion to Hydrocarbons”,Chemical Engr.Sci.35 619-622(1980) .
[18] Anthony,R.G.,“A Kinetic Model for Methanol Conversion to Hydrocarbons”,Chemical Engr.Sci.36,789(1981) .
[19] Van der Burg J.P.,J.P.Wolthuizen and J.H.C.Van Hooff,“The Conversion of Dimethylether to Hydrocarbons on Zeolite H-ZSM-5-The Mechanism for Formation of Primary Olefins”Presented at International Conference on Zeolites,Naples(1980) .
[20] Mihail,R.,S.Straja,Gh.Mariv,G.Muses and Gr.Pop,“A Kinetic Model for Methanol Conversion to Hydrocarbons”,Polytechnic Institute-Bucharest,Dept.of Chemical Engineering and Institute of Chemical and Biochemical Energy,Personal Communications(1982) .
[21] Hall.W.K.,F.E.Lutinski and H.R.Gerberick,J.of Catalyst,1964,3,512.
2019 版权所有©东北石油大学 | 地址:黑龙江省大庆市高新技术产业开发区学府街99号 | 邮政编码:163318
信息维护:学报 | 技术支持:现代教育技术中心
网站访问量: