程双玲,伍如意

• 1:美国西部研究所

• 2:大庆石油学院石油地化研究室 博士

摘要(Abstract)：

本课题的中心是对绿河油页岩经4O0℃、425℃及440℃恒温热解的液体产物进行分析鉴定。根据对初始裂解产物中热解沥青的性质分析,推测绿河油页岩干酪根的结构特性。用反应动力学曲线,计算各组分生成的反应速度常数和活化能。此外,在分析生成油中的脂肪烃类时,可用几种热成熟指标来描述所做的热解过程。

关键词(KeyWords)：恒温热解;干酪根;反应速度常数;活化能;沥青

Abstract:

Keywords:

基金项目(Foundation):

作者(Author):程双玲,伍如意

Email:

参考文献(References)：

• [1] Hubbard, A. B. and W. E. Robinson. 1950． A Thermal Decomposition Study of Colorado Oil Shale. USBM RI 4744．

• [2] Conn, P. J., H. J. Rollison, and F. P. Miknis. 1984． Comparison of Isothermal. Kerogen Decomposition Using Reactors with Different Heat-Up Rates. Laramie, WY, DOE Report, DOE/FE/60177--1791．

• [3] Smith, J. W. 1961． Ultimate Composition of Organic Materal in Green River Oil Shale. USBM RI 5725．

• [4] Chong, Shuang-Ling, J. J. Cummins and W. E. Robinson. 1976． Fractionation of Soluble Extracts Obtained from Kerogen Thermal Degradation with CO and H_2O. Preprint of Fuel Division, ACS meeting, 21 (6) : 265．

• [5] Mckay, John F. and Shuang-Ling Cheng. 1983． Characterization of Organic Matter Recovered from Green River Oil Shale at Tempeatures of 400℃ and Below. Liq. Fuel Tech., 1 (4) : 289．

• [6] Chong, Shuang-Ling. 1980． Carboxylic Acids from the Treatment of Green River Oil Shale with Carbon Monoxide and Water In T. F. Yen, F. K. Kawahara and R. Hertzberg (ed.), Chemical and Geochemical Aspects of Fossil Energy Extraction. Ann Arbor Science, Chapter 9, pp. 143．

• [7] Chong, Shuang-Ling and J. F. Mckay. 1984． Extractable Metal Salts of Carboxylic Acids in Green River Oil Shale. Fuel, 63: 303．

• [8] Miknis, F. P. and R. E. Robertson. Characterization of DOE Reference Oil Shale: Ⅰ. Mahogany Znce, Parachute Creek Member, Green River Formation Oil Shale, and Clegg Creek Member, New Albany Shale. in review.

• [9] Noble, Richard, D., W. F. Tucker, and H. G. Harris. 1982． Isothermal Oil Shale Pyrolysis. 1． Oil Generation and Composition at Various Pressures. Fuel, 61: 482．