作者:伍如意,程双玲,Francis P.Miknis 时间:1988-01-01 点击数:
伍如意,程双玲,Francis P.Miknis
1:大庆石油学院
2:大庆石油学院
3:美国西部研究所
摘要(Abstract):
本文研究了油页岩经费歇尔(Fischer)热解得到的生成油,用以比较产于世界几大洲、不同沉积的12种油页岩。采用分离技术将热解生成油按化合物类型分开,分出的馏份用气相色谱鉴定。另外还比较了油页岩和页岩油的元素组成以及页岩样品的固体~(13)C核磁共振波谱。结果表明,第三纪、湖相沉积油页岩热解后,生成含有大量从低碳数到高碳数正构烷烃的石蜡基页岩油;而地质年代相对古老的海相油页岩,却生成只含低碳数烷烃的芳香基页岩油:
关键词(KeyWords):油页岩;费歇尔热解生成油;沉积环境;气相色谱
Abstract:
Keywords:
基金项目(Foundation):
作者(Author):伍如意,程双玲,Francis P.Miknis
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参考文献(References):
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[2] Tissot, B. P., and M. Vandenbroucke. "Geochemistry and Pyrolysis of oil shales." in Geochemistry and Chemistry of Oil Shales, F. P. Miknis and J. F. Mckay, Eds; ACS Symposium-Series 230, American Chemical Society, Washington, DC, 1983, 1.
[3] Nuttall, H. E., Tian-Min Guo, S. Schrader, and D. S. Thakur. "Pyrolysis Rinetics of several key world oil shales." in Geochemistry and Chemistry of Oil Shales, F. P. Miknis and J. F. Mckay, Eds; ACS Symposium-Series 230, American Chemical Society, Washington, DC, 1983, 269.
[4] Miknis, F. P., D. A. Netzel, J. W. Smith, M. A. Mast, and G. E. Maciel. "~(13) C NMR measurements of the genetic potentials of oil shales." Geochim. et Cosmochim. Acta, 1982, 46, 977.
[5] Anders, D. E., and W. E. Robinson. "Cycloakane constituents of the bitumen from Green River oil shale." Geochim et Cosmochim. Acta, 1971, 35, 661.
[6] 秦匡宗、劳永新.“茂名和抚顺油页岩组成结构的研究Ⅰ.有机质的芳碳结构”.燃料化学学报,1985,13,No.2:133
[7] 黄第藩等.陆相有机质演化和成烃机理.北京:石油工业出版社,1984。
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