徐艳姝;姜祥成;

• 1:大庆油田有限责任公司勘探开发研究院

摘要(Abstract)：

为考察石油磺酸盐中未磺化油对复合驱体系性能的作用,分析未磺化油对界面张力、黏度、抗油砂和油相吸附、驱油效率的影响.结果表明:石油磺酸盐复合驱体系与原油之间超低界面张力的形成,主要依靠石油磺酸盐中未磺化油与原油之间的混相作用;在强碱条件下,石油磺酸盐中的未磺化油使得体系的黏度明显低于具有相同聚合物质量浓度的重烷基苯磺酸盐强碱复合驱体系的,也使得石油磺酸盐复合驱体系的抗油相吸附能力明显弱于重烷基苯磺酸盐强碱复合体系的;未磺化油的混相作用对石油磺酸盐复合驱体系提高驱油效率至关重要.

关键词(KeyWords)：石油磺酸盐;未磺化油;混相作用;复合驱体系;吸附能力;驱油效率

Abstract:

Keywords:

基金项目(Foundation):中国石油天然气股份有限公司项目(2008E-1206)

作者(Author):徐艳姝;姜祥成;

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参考文献(References)：

• [1]程杰成,廖广志,杨振宇,等.大庆油田三元复合驱矿场试验综述[J].大庆石油地质与开发,2001,20(2):46-49.Cheng Jiecheng,Liao Guangzhi,Yang Zhenyu,et al.Pilot test of ASP flooding in Daqing oilfield[J].Petroleum Geology&Oilfield Development in Daqing,2001,20(2):46-49.

• [2]程杰成,王德民,李群,等.大庆油田三元复合驱矿场试验动态特征[J].石油学报,2002,23(6):37-40.Cheng Jiecheng,Wang Demin,Li Qun,et al.Field test performance of alkaline surfactant polymer flooding in Daqing oilfield[J].Acta Petrolei Sinica,2002,23(6):37-40.

• [3]郭万奎,程杰成,廖广志.大庆油田三次采油技术研究现状及发展方向[J].大庆石油地质与开发,2002,21(3):1-7.Guo Wankui,Cheng Jiecheng,Liao Guangzhi.Present situation and direction of tertiary recovery technique in the future in Daqing oilfield[J].Petroleum Geology&Oilfield Development in Daqing,2002,21(3):1-7.

• [4]周万富,张士诚,王庆国,等.强碱三元复合驱长岩心模拟实验中成垢离子变化规律[J].大庆石油学院学报,2010,34(2):77-80.Zhou Wanfu,Zhang Shicheng,Wang Qingguo,et al.Variation patterns of precipitable ions during the process of alkaline/surfactant/polymer flooding upon the long core[J].Journal of Daqing Petroleum Institute,2010,34(2):77-80.

• [5]李金玲,李天德,李睿,等.三元复合驱硅垢除垢剂在螺杆泵举升井中的应用[J].大庆石油学院学报,2005,29(1):28-29.Li Jinling,Li Tiande,Li Rui,et al.Application of silicon containing scale remover to screw pump lift in ASP flooding[J].Journal of Daqing Petroleum Institute,2005,29(1):28-29.

• [6]王玉普,程杰成.三元复合驱过程中的结垢特点和机采方式适应性[J].大庆石油学院学报,2003,27(2):20-22.Wang Yupu,Cheng Jiecheng.The scaling characteristics and adaptability of mechanical recovery during ASP flooding[J].Journal of Daqing Petroleum Institute,2003,27(2):20-22.

• [7]程杰成,张月先,包亚臣.烷基苯磺酸盐弱碱体系对油水界面张力的影响[J].大庆石油学院学报,2004,28(3):37-39.Cheng Jiecheng,Zhang Yuexian,Bao Yachen.Effect of Na2CO3/Alkyl Benzene Sulfonate/Polymer system on interfacial tension be-tween oil and water[J].Journal of Daqing Petroleum Institute,2004,28(3):37-39.

• [8]戴雪花.嘛甸油田北东块二类油层三元复合驱油试验效果与认识[J].大庆石油地质与开发,2010,29(4):152-155.Dai Xuehua.Test effects and understandings of ASP flooding in second-class oil layers in NE block of Lamadian oilfield[J].Petroleum Geology&Oilfield Development in Daqing,2010,29(4):152-155.

• [9]杨迎花,邓启刚,毛庆云.石油磺酸盐的合成及其复配体系在三次采油中的应用[J].齐齐哈尔大学学报,2002(4):48-49.Yang Yinghua,Deng Qigang,Mao Qingyun.The synthesis of petroleum sulfonates and the application of its complex system in enhanced oil recovery[J].Journal of Qiqiha′er universities,2002(4):48-49.

• [10]于芳,范维玉,南国枝,等.一种驱油用石油磺酸盐的制备及评价[J].石油炼制与化工,2007(4):11-12.Yu Fang,Fan Weiyu,Nan Guozhi,et al.Preparration and evaluation of petroleum sulphonate for oil displacement[J].Petroleum Processing and Petrochemicals,2007(4):11-12.

• [11]史俊,刘祥.重芳烃石油磺酸盐驱提高原油采收率试验研究[J].西安石油学院学报,2001,16(4):59-62.Shi Jun,Liu Xiang.Experimental study of heavy aromatic petroleum sulfonate improving oil recovery factor[J].Journal of Xi′an Petroleum Institute,2001,16(4):59-62.

• [12]何涛,李红英,何右安.三次采油用石油磺酸盐的研究进展[J].精细石油化工进展,2003,4(1):8-11.He Tao,Li Hongying,He Youan.Research development of petroleum sulfonates used in EOR[J].Advances in Fine Petrochemicals,2003,4(1):8-11.

• [13]韩霞,王建华,管善峰,等.驱油用石油磺酸盐的研究及其应用[J].日用化学品科学,2008,31(11):38-41.Han Xia,Wang Jianhua,Guan Shanfeng,et al.Research and application of petroleum sulfonate as oil displacement agents[J].Detergent&Cosmetics,2008,31(11):38-41.

• [14]段友智,李阳,范维玉,等.石油磺酸盐组成及其油水体系界面张力的关系研究[J].石油化工高等学校学报,2009,22(3):46-50.Duan Youzhi,Li Yang,Fan Weiyu,et al.Composition of petroleum sulfonates and the influence to interfatial tension of oil/water system[J].Journal of Petrochemical Universities,2009,22(3):46-50.

• [15]王小泉,卜绍峰.重芳烃磺酸盐在砂岩表面相对接触角的测定[J].油田化学,2004,21(3):280-283,289.Wang Xiaoquan,Bu Shaofeng.Measuring relative contact angle of heavy aromatics sulfonate surfaces[J].Oilfield Chemistry,2004,21(3):280-283,289.

• [16]聂振霞.胜利石油磺酸盐在史深100油田的应用[J].大庆石油学院学报,2011,35(3):81-84.Nie Zhenxia.Application of petroleum sulfonate of Shengli oilfields to Shishen 100oilfield[J].Journal of Daqing Petroleum Institute,2011,35(3):81-84.

• [17]Hill H J,Reisberg J,Stegemeier G L.Aqueous surfactant systems for oil recovery[J].Journal of Petroleum Technology,1973,25(2):186-194.

• [18]Gale W W,Sandvik E I.Tertiary surfactant flooding:petroleum sulfonate composition-fficacy studies[J].Society of Petroleum Engineers,1973,13(4):191-199.