吴红军;阮琴;王宝辉;腾佳;付波;

• 1:大庆石油学院化学化工学院新能源化学与环境科学实验室

• 2:中国石油锦州石化公司

摘要(Abstract)：

为制备高性能析氧电极,采用热分解法在400℃温度下制备Ti/RuO2(x)-Co3O4(1-x)(0≤x≤1,x为Ru的摩尔分数)复合氧化物电极,通过电极开路电压、循环伏安曲线及极化曲线等分析其在1.0mol/LKOH溶液中的析氧催化活性及析氧动力学.结果表明,摩尔分数为10%的RuO2使电极催化活性急剧变化,摩尔分数为50%的RuO2复合氧化物电极具有最大的伏安电荷(429.63mC.cm-2)、最高的表面粗糙度(1786),其析氧性能最佳;Ti/Co3O4在高、低过电位区域电极对OH-的反应级数分别近似为1.0和2.0,含RuO2电极反应级数均为1.0.

关键词(KeyWords)：二氧化钌;四氧化三钴;电催化活性;析氧性能;复合氧化物;热分解法

Abstract:

Keywords:

基金项目(Foundation):国家自然科学基金项目(50476091);;

黑龙江省自然科学基金项目(B200401)

作者(Author):吴红军;阮琴;王宝辉;腾佳;付波;

Email:

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