作者:邓军;张洪升; 时间:2007-01-01 点击数:
邓军;张洪升;
1:大庆应用技术研究院
2:大庆应用技术研究院 黑龙江大庆163316
3:黑龙江大庆163316
摘要(Abstract):
选择稀土金属Tb作为功能性的金属中心与有机配体均苯三甲酸构筑了一种新型稀土金属有机羧酸骨架材料Tb(BTC)(DMF)(DMSO).通过对化合物Tb(BTC)(DMF)(DMSO)的单晶结构与荧光性、热稳定性和吸附性分析,表明该化合物在催化、吸附和荧光材料领域有潜在的应用前景.
关键词(KeyWords):稀土金属Tb;ABW拓扑结构;荧光性;热稳定性
Abstract:
Keywords:
基金项目(Foundation):大庆高新区创新基金项目(DQGX06NL016)
作者(Author):邓军;张洪升;
Email:
参考文献(References):
[1]HOSKI NS B F,ROBSON R.Infinite polymeric frameworks consisting of three di mensionally linked rod-like segments[J].J.Am.Chem.Soc,1989,111:5962-5964.
[2]SUNJ Y,WENG L H,ZHOU Y M,et al.QMOF-1and QMOF-2:three-di mensional metal±organic openframeworks with a qu-artzlike topology[J].Angew.Chem.Int.Ed.,2002,41:4471-4473.
[3]CHEN Bang-lin,EDDAOUDI M.,REI NEKE T M,et al.Cu2(ATC)a6H2O:Design of open metal sites in porous metal-organic crystals(ATC:1,3,5,7-Adamantane Tetracarboxylate)[J].J.Am.Chem.Soc,2000,122:11559-11560.
[4]KIRITSIS V,Michaelides A,Skoulika S,etal.Assembly of a porous three-di mensional coordination polymer:crystal structure of{[La2(adipate)3(H2O)4]6H2O}n[J].Inorg.Chem,1998,37:3407-3410.
[5]DEVIC T,SERRE C,AUDEBRAND N,et al.MIL-103,a3-Dlanthanide-based metal organic framework withlarge one-di men-sional tunnels and a high surface area[J].J.Am.Chem.Soc,2005,127:12788-12789.
[6]ZHAO Bin,CHEN Xiao-yan,CHENG Peng,et al.Coordination polymers containing1Dchannels as selectiveluminescent pobes[J].J.Am.Chem.Soc,2004,126:15394-15395.
2019 版权所有©东北石油大学 | 地址:黑龙江省大庆市高新技术产业开发区学府街99号 | 邮政编码:163318
信息维护:学报 | 技术支持:现代教育技术中心
网站访问量: