作者:赵迪斐;郭英海;任呈瑶;李艳芳; 时间:2018-01-01 点击数:
赵迪斐;郭英海;任呈瑶;李艳芳;
1:中国矿业大学资源与地球科学学院
2:中国矿业大学煤层气资源与成藏过程教育部重点实验室
3:南京大学地球科学与工程学院
4:中国石化石油勘探开发研究院无锡石油地质研究所
摘要(Abstract):
基于古交地区山西组页岩储层样品,利用场发射扫描电镜、高压压汞、低温氮吸附、X线衍射等实验,探究过渡相页岩纳米级孔隙的发育特征及影响因素。结果表明:研究区储层孔隙主要包括有机孔隙、黏土矿物孔隙、骨架矿物孔隙、微裂隙四类,以中孔为主,发育多种形貌;四类孔隙所占储集空间比例分别为22.4%、44.0%、27.2%、6.4%。过渡相页岩非均质性显著,孔隙分形分维值平均近2.7,显示非均质程度较强、空间结构复杂。孔隙孔径与总孔体积减小,比表面积增大,纳米孔及吸附点位增多;有机碳与石英质量分数增多,黏土矿物质量分数减少,孔隙发育程度增强。水进体系域下形成的凝缩层及高位体系域中的泥炭沼泽—分流间洼地、泥炭沼泽—分流间湾沉积组合是优质页岩储层发育的有利层位。
关键词(KeyWords):过渡相页岩;纳米孔特征;孔隙结构;孔隙分类;定量评价;山西组;古交地区
Abstract:
Keywords:
基金项目(Foundation):国家自然科学基金项目(41772130);; 国家重点基础研究发展计划(973计划)项目(2012CB214702);; 山西省煤基重点科技攻关项目(MQ201402);; 教育部重点实验室开放基金项目(2015-007);; 中国矿业大学大学生科研创新项目(CSA2018-ZK05)
作者(Author):赵迪斐;郭英海;任呈瑶;李艳芳;
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参考文献(References):
[1] Jiang S,Zhang J,Jiang Z,et al.Geology,resource potentials,and properties of emerging and potential China shale gas and shale oil plays[J].Interpretation,2015,3(2):SJ1-SJ13.
[2] Loucks R G,Reed R M,Ruppel S C,et al.Morphology,genesis,and distribution of nanometer-scale pores in siliceous mudstones of the mississippian barnett shale[J].Journal of Sedimentary Research,2009,79(12):848-861.
[3] Zou C,Yang Z,Dai J,et al.The characteristics and significance of conventional and unconventional Sinian-Silurian gas systems in the Sichuan basin,central China[J].Marine and Petroleum Geology,2015,64:386-402.
[4] Javadpour F.Nanopores and apparent permeability of gas flow in mudrocks(shales and siltstone)[J].Journal of Canadian Petroleum Technology,2009,48(8):16-21.
[5] Xi Z,Tang S,Zhang S,et al.Pore structure characteristics of marine-continental transitional shale:A case study in the Qinshui basin,China[J].Energy&Fuels,2017,31(8):7854-7866.
[6] Chen Q,Zhang J,Tang X,et al.Relationship between pore type and pore size of marine shale:An example from the Sinian-Cambrian formation,upper Yangtze region,south China[J].International Journal of Coal Geology,2016,158:13-28.
[7] Huang Y,Yang R,Xiao Z,et al.Influencing factors of shale gas-bearing property of lower Cambrian Niutitang formation in northwestern Hunan[J].Lithologic Reservoirs,2015,27(4):11-16.
[8]梁超,姜在兴,杨镱婷,等.四川盆地五峰组—龙马溪组页岩岩相及储集空间特征[J].石油勘探与开发,2012,39(6):691-698.Liang Chao,Jiang Zaixing,Yang Yiting,et al.Characteristics of shale lithofacies and reservoir space of the Wufeng-Longmaxi formation,Sichuan basin[J].Petroleum Exploration and Development,2012,39(6):691-698.
[9]王玉满,董大忠,李建忠,等.川南下志留统龙马溪组页岩气储层特征[J].石油学报,2012,33(4):551-561.Wang Yuman,Dong Dazhong,Li Jianzhong,et al.Reservoir characteristics of shale gas in Longmaxi formation of the lower Silurian,southern Sichuan[J].Acta Petrolei Sinica,2012,33(4):551-561.
[10]刘树根,马文辛,Luba J,等.四川盆地东部地区下志留统龙马溪组页岩储层特征[J].岩石学报,2011,27(8):2239-2252.Liu Shugen,Ma Wenxin,Luba J,et al.Characteristics of the shale gas reservoir rocks in the lower Silurian Longmaxi formation,east Sichuan basin,China[J].Acta Petrologica Sinica,2011,27(8):2239-2252.
[11] Yang R,He S,Hu Q,et al.Geochemical characteristics and origin of natural gas from Wufeng-Longmaxi shales of the Fuling gas field,Sichuan basin(China)[J].International Journal of Coal Geology,2017,171:1-11.
[12] Luo Q,Zhong N,Dai N,et al.Graptolite-derived organic matter in the Wufeng-Longmaxi formations(upper Ordovician-lower Silurian)of southeastern Chongqing,China:Implications for gas shale evaluation[J].International Journal of Coal Geology,2016,153(1/2):87-98.
[13] Guo T,Zeng P.The structural and preservation conditions for shale gas enrichment and high productivity in the Wufeng-Longmaxi formation,southeastern Sichuan basin[J].Energy Exploration&Exploitation,2015,33(3):259-276.
[14] Xi Z,Tang S,Zhang S,et al.Nano-scale pore structure of marine-continental transitional shale from Liulin area,the eastern margin of Ordos basin,China[J].Journal of Nanoscience&Nanotechnology,2017,17(9):6109-6123.
[15] Ding W,Zhu D,Cai J,et al.Analysis of the developmental characteristics and major regulating factors of fractures in marine-continental transitional shale-gas reservoirs:A case study of the carboniferous-permian strata in the southeastern Ordos basin,central China[J].Marine&Petroleum Geology,2013,45(4):121-133.
[16] Zhang J,Li X,Zhang X,et al.Geochemical and geological characterization of marine-continental transitional shales from Longtan formation in Yangtze area,south China[J].Marine&Petroleum Geology,2018,96(5):1-15.
[17]梁冰,石迎爽,孙维吉,等.中国煤系“三气”成藏特征及共采可能性[J].煤炭学报,2016,41(1):167-173.Liang Bing,Shi Yingshuang,Sun Weiji,et al.Reservoir forming characteristics of"the three gases"in coal measure and the possibility of commingling in China[J].Journal of China Coal Society,2016,41(1):167-173.
[18]秦勇,申建,沈玉林.叠置含气系统共采兼容性——煤系“三气”及深部煤层气开采中的共性地质问题[J].煤炭学报,2016,41(1):14-23.Qin Yong,Shen Jian,Shen Yulin.Joint mining compatibility of superposed gas bearing systems:A general geological problem for extraction of three natural gases and deep CBM in coal series[J].Journal of China Coal Society,2016,41(1):14-23.
[19] He J,Zhang X,Yan J,et al.Resource potential for Co-exploration and joint exploitation on unconventional gas in coal measure in China[J].Open Fuels&Energy Science Journal,2015,8(1):361-367.
[20]黄磊,申维.页岩气储层孔隙发育特征及主控因素分析:以上扬子地区龙马溪组为例[J].地学前缘,2015,22(1):374-385.Huang Lei,Shen Wei.Characteristics and controlling factors of the formation of pores of a shale gas reservoir:A case study from Longmaxi of the upper Yangtze region,China[J].Earth Science Frontiers,2015,22(6):374-385.
[21]赵迪斐,郭英海,朱炎铭,等.海相页岩储层微观孔隙非均质性及其量化表征[J].中国矿业大学学报,2018,47(2):1-12.Zhao Difei,Guo Yinghai,Zhu Yanming,et al.Micropore heterogerneity of marine shale reservoirs and its quantitative characterization[J].Journal of China University of Mining and Technology,2018,47(2):1-12.
[22]曹涛涛,宋之光,罗厚勇,等.下扬子地区二叠系海陆过渡相页岩孔隙体系特征[J].天然气地球科学,2016,27(7):1332-1345.Cao Taotao,Song Zhiguang,Luo Houyong,et al.Pore system characteristics of Permian transitional shale reservoirin the lower Yangtze region,China[J].Natural Gas Geoscience,2016,27(7):1332-1345.
[23] Chen Q,Zhang J,Tang X,et al.Pore structure characterization of the lower Permian marine-continental transitional black shale in the southern north China basin,central China[J].Energy&Fuels,2016,30(12):10092-10105.
[24]孙玉琦.古交矿区山西组沉积环境及其对煤层气富集的影响[D].徐州:中国矿业大学,2015.Sun Yuqi.Sedimentary environment of Shanxi formation and its impact on CBM enrichment in Gujiao Mining area[D].Xuzhou:China University of Mining and Technology,2015.
[25] Wang Z H,Hu S D,Guo P,et al.Molecular simulations of the adsorption of shale gas in organic pores[J].Materials Research Innovations,2015,19(S5):106-111.
[26]杨峰,宁正福,胡昌蓬,等.页岩储层微观孔隙结构特征[J].石油学报,2013,34(2):301-311.Yang Feng,Ning Zhengfu,Hu Changpeng,et al.Characterization of microscopic pore structures in shale reservoirs[J].Acta Petrolei Sinica,2013,34(2):301-311.
[27] Li Q H,Chen M,Jin Y,et al.Indoor evaluation method for shale brittleness and improvement[J].Chinese Journal of Rock Mechanics&Engineering,2012,31(8):1680-1685.
[28]赵迪斐,郭英海,解徳录,等.龙马溪组下部页岩储层孔隙结构特征与评价方案——以重庆南川三泉剖面泉浅1井为例[J].煤炭学报,2014,39(增刊2):452-457.Zhao Difei,Guo Yinghai,Xie Delu,et al.Characteristics and evaluation scheme of shales reservoir pores of the lower part of Longmaxi formation:A case study at Chongqing Nanchuan Sanquan Quanqian well one[J].Journal of China Coal Society,2014,39(Supp.2):452-457.
[29]严继民,张启元.吸附与凝聚:固体的表面与孔[M].北京:科学出版社,1979.Yan Jimin,Zhang Qiyuan.Adsorption and condensation:Surface and pore of solids[M].Beijing:Science Press,1979.
[30] Donaldson E C,Kendall R F,Baker B A,et al.Surface-area measurement of geologic materials[J].SPE Journal,1975,15(2):111-116.
[31] Brunauer S,Deming L S,Deming W E,et al.On a theory of the van der Waals adsorption of gases[J].Journal of the American Chemical Society,1940,62(7):1723-1732.
[32] Loucks R G,Reed R M,Ruppe S C,et al.Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix related mudrock pores[J].AAPG Bulletin,2012,96(6):1071-1098.
[33]郭英海,赵迪斐.微观尺度海相页岩储层微观非均质性研究[J].中国矿业大学学报,2015,44(2):300-307.Guo Yinghai,Zhao Difei.Analysis of micro-scale heterogeneity characteristics in marine shale gas reservoir[J].Journal of China University of Mining&Technology,2015,44(2):300-307.
[34] Tang X,Jiang Z,Jiang S,et al.Heterogeneous nanoporosity of the Silurian Longmaxi formation shale gas reservoir in the Sichuan basin using the Qemscan,FIB-SEM,and nano-CT methods[J].Marine&Petroleum Geology,2016,78:99-109.
[35]徐祖新.基于CT扫描图像的页岩储层非均质性研究[J].岩性油气藏,2014,26(6):46-49.Xu Zuxin.Heterogeneity of shale reservoirs based on CT images[J].Lithologic Reservoirs,2014,26(6):46-49.
[36]傅雪海,秦勇,薛秀谦,等.煤储层孔、裂隙系统分形研究[J].中国矿业大学学报,2001,30(3):11-14.Fu Xuehai,Qin Yong,Xue Xiuqian,et al.Reseach on fractal of pore and fracture-structure of coal reservoirs[J].Journal of China University of Mining and Technology,2001,30(3):11-14.
[37]杨峰,宁正福,王庆,等.页岩纳米孔隙分形特征[J].天然气地球科学,2014,25(4):618-623.Yang Feng,Ning Zhengfu,Wang Qing,et al.Fractal characteristics of nanopore in shales[J].Natural Gas Geoscience,2014,25(4):618-623.
[38] Pfeiferper P,Avnir D.Chemistry nonintegral dimensions between two and three[J].Journal of Chemical Physics,1983,79(7):3369-3558.
[39] Chalmers G R L,Bustin R M.On the effects of petrographic composition on coalbed methane sorption[J].International Journal of Coal Geology,2007,69:288-304.
[40] Yang Y,Aplin A C.Influence of lithology and compaction on the pore size distribution and modelled permeability of some mudstones from the Norwegian margin[J].Marine&Petroleum Geology,1998,15:163-175.
[41] Liu X J,Xiong J,Liang L.Investigation of pore structure and fractal characteristics of organic-rich Yanchang formation shale in central China by nitrogen adsorption/desorption analysis[J].Journal of Natural Gas Science&Engineering,2014,22(7):62-72.
[42]赵迪斐,郭英海,解徳录,等.基于低温氮吸附实验的页岩储层孔隙分形特征[J].东北石油大学学报,2014,38(6):100-108.Zhao Difei,Guo Yinghai,Xie Delu,et al.Fractal characteristics of shale reservoir pores based on nitrogen adsorption[J].Journal of Northeast Petroleum University,2014,38(6):100-108.
[43]赵迪斐,郭英海,白万备,等.沉积环境对优质页岩储层发育的控制作用——以渝东南地区龙马溪组为例[J].河南理工大学学报:自然科学版,2018,37(4):37-47.Zhao Difei,Guo Yinghai,Bai Wanbei,et al.The controlling mechanism of sedimentary environment on high quality shale reservoir:Using shale reservoirs of Longmaxi formation in southeast Chongqing area as an example[J].Journal of Henan Polytechnic University:Natural Science Edition,2018,37(4):37-47.
[44]赵迪斐,郭英海,杨玉娟,等.渝东南下志留统龙马溪组页岩储集层成岩作用及其对孔隙发育的影响[J].古地理学报,2016,18(5):843-856.Zhao Difei,Guo Yinghai,Yang Yujuan,et al.Shale reservoir diagenesis and its impacts on pores of the lower Silurian Longmaxi formation in southeastern Chongqing[J].Journal of Palaeogeography,2016,18(5):843-856.
[45]苏驰.古交矿区太原组层序地层与含气特征研究[D].徐州:中国矿业大学,2016.Su Chi.Stucy on the sequence stratigraphy and the gas characteristics of Taiyuan formation in Gujiao mine area[D].Xuzhou:China University of Mining and Technology,2016.
[46]时尚科.古交杨庄勘探区山西组沉积演化及聚煤规律[D].徐州:中国矿业大学,2016.Shi Shangke.Study on the sedimentary evolution and coal accumulation pattern of Shanxi formation in Gujiao Yangzhuang mine[D].Xuzhou:China University of Mining and Technology,2016.
[47]徐占杰.沁水盆地北部煤层气同位素地球化学及成因研究[D].北京:中国矿业大学(北京),2017.Xu Zhanjie.Study on isotopic geochemistry and origins of coalbed methane in the northern Qinshui basin[D].Beijing:China University of Mining and Technology(Beijing),2017.
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